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Iodide


- Potassium Iodide
- 2-Iodoxybenzoic Acid
- Dess Martin Periodinane
- Iodobenzene Diacetate
- Iodobenzene Dichloride
- Iodosylbenzene
- 1, 4-Diiodobenzene
- 2-Lodophenol
- 2-Hydroxyiodobenzene
- 3, 5-Di Lodosalicylic Acid
- 4-Chloro Iodo Benzene
- 4-Iodoanisole
- P-Hydroxyiodobenzene
- 4-Hydroxyphenyl Iodide
- 4-Iodotoluene
- Sodium Metaperiodate
- 5-Iodo-2-Methylbenzoic Acid
- Cuprous Iodide
- Diphosphorus Tetraiodide
- Iodo Ethane
- Ferrous Iodide
- Hydriodic Acid
- Hydroiodic Acid
- Iodine Monochloride
- Iodure De Trimethyloxosulfonium
- Iodoacetic acid
- Methyl Iodide
- Methyl-2-iodo Benzoate
- N-Butyl Iodide
- 1-Lodobutano
- Orthoperiodic acid
- Potassium Meta Periodate
- Cadmium Iodide
- Lithium Iodide
- Potassium Mercuric Iodide
- Silver Iodide
- Sodium Iodide
- IBX acid
- Diphenyliodonium Iodide
- Diacetoxyiodobenzene
- Iodobenzene Bichloride
- Iodosobenzene
- 2-Iodobenzoic Acid
- O-Iodophenol
- O-Hydroxyiodobenzene
- 4-Bromo Iodo Benzene
- 4-Iodoaniline
- 4-Iodophenol
- 4-Hydroxyiodobenzene
- P-Iodophenol
- 1-Iodo-4-Methylbenzene P-Iodotoluene
- Sodium Periodatemeta
- Ammonium Iodide
- Copper Iodide
- Ethyl Iodide
- Ethylenediamine Dihydriodide
- Iron Iodide
- Hydrogen Iodide
- Iodic Acid
- Trimethylsulfoxonium Iodide
- Iodine Pentoxide
- Iodobenzene
- Iodomethane
- Butyl iodide
- 1-Iodobutane
- Periodic Acid
- Metaperiodic Acid
- Zinc Iodide
- Mercuric Iodide Red
- Barium Iodide
- Tetra- N- Butylammonium Bromide
- Tetramethylammonium Iodide


  2-Iodoxybenzoic Acid

IBX acid or 2-Iodoxybenzoic acid is an organic compound used in organic synthesis as an oxidizing agent. This Periodinane is especially suited to oxidize alcohols to aldehydes. The IBX acid is prepared from 2-iodobenzoic acid, potassium bromate and sulfuric acid.[1] Frigerio and co-workers have also demonstrated, in 1999 that potassium bromate may be replaced by commercially available oxone.



  IBX acid

2-Iodoxybenzoic acid (IBX), the impact-sensitive intermediate in the synthesis of the Dess-Martin periodinane, is available in a DMSO solution and is used as an oxidizing agent.



  Dess Martin Periodinane

Dess-Martin periodinane is a chemical reagent used to oxidize primary alcohols to aldehyde and secondary alcohols to ketones.[1][2] This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions, shorter reaction times, higher yields, and simplified workups. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin.



  Diphenyliodonium Iodide

Aziridination of N-tosylimines with activated methylene compounds induced by iodobenzene diacetate [PhI(OAc)2] and tetra butyl ammonium bromide [Bu4NBr] afforded the corresponding 2,2-difunctionalized aziridines in good yields with the aid of a catalytic amount of base. The reaction is hypothesized to proceed via a tandem nucleophilic addition-oxidative cyclization pathway.



  Iodobenzene Diacetate

The concept of hypervalent iodine was developed by J.J. Musher in 1969. In order to accommodate the excess of electrons in hypervalent compounds the 3-center-4-electron bond was introduced in analogy with the 3-center-2-electron bond observed in electron deficient compounds. One such bond exists in iodine(III) compounds and two such bonds reside in iodine(V) compounds.




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