Many examples of ionic sulfates are
known, and many of these are highly soluble in water. Exceptions include
calcium sulfate, strontium sulfate, and barium sulfate, which are poorly
soluble. The barium derivative is useful in the gravimetric analysis of
sulfate: one adds a solution of, perhaps, barium chloride to a solution
containing sulfate ions. The appearance of a white precipitate, which is
barium sulfate, indicates that sulfate anions are present.
The sulfate ion can act as a ligand attaching either by one oxygen
(monodentate) or by two oxygens as either a chelate or a bridge.[1] An
example is the neutral metal complex PtSO4P(C6H5)32 where the sulfate ion is
acting as a bidentate ligand. The metal-oxygen bonds in sulfate complexes
can have significant covalent character




