Calcium hexaboride (sometimes calcium boride) is a compound of calcium and boron with the chemical formula cab6. It is an important material due to its high electrical conductivity, hardness, chemical stability, and melting point.

Cerium hexaboride (CeB6, also called cerium boride, CeBix, CEBIX, and (incorrectly) CeB) is an inorganic chemical, a boride of cerium. It is a refractory ceramic material. It has low work function and one of the highest electron emissivity known, and is stable in vacuum.

Lanthanum hexaboride (LaB6, also called lanthanum boride and LaB) is an inorganic chemical, a boride of lanthanum. It is a refractory ceramic material that has a melting point of 2210 °C, and is insoluble in water and hydrochloric acid.