Even though boric acid adds hydroxide to
form B(OH)4-, you may find for pKa values and other
calculations, the fictitious ions are easier to use. Thus for a typical
polyprotic acid, the deprotonation series dihydrogen borate [H2BO3-;],
hydrogen borate [HBO32-] and borate [BO33-]
may be written as pH increases.
Boric acid can be used to form many polymeric ions. The tetraborate ion, B4O72-,
is very common; the hydrogen tetraborate ion, HB4O7-,
as well as triborate and pentaborate, are also seen. The various metaborate
ions have an empirical formula of BO2-, and form metaborate
compounds. Formation of these complicated, potentially infinite network
structures is extensive, perhaps surpassed only by the silicates.
Common borate salts include sodium metaborate, NaBO2, and sodium
tetraborate, Na2B4O7. The latter also
occurs naturally as the hydrous mineral borax, Na2B4O7·10H2O.
Boron, California contains large borax deposits and is used extensively for
borate mining. The Atacama Desert in Chile also contains mineable borate
concentrations.





Borax
(from Persian burah[1][2]), also called sodium borate, or
sodium tetraborate, or disodium tetraborate, is an
important boron compound, a mineral, and a salt of boric acid. It is
usually a white powder consisting of soft colorless crystals that
dissolve easily in water.