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Intermediates for x-rays


- 5-Nitroisophthalic Acid
- 5-nitro Isophthalic Acid Dimethyl Ester
- 5-Nitro-1, 3-Benzenedicarboxylic Acid
- 3, 5-Dinitrobenzoic acid
- 5-Nitro-1, 3-Benzenedicarboxylic Acid
- 5-nitro Isophthalic Acid Monomethyl Ester
- Mono-Methyl 5-Nitro-Isophthalate


  5-Nitroisophthalic Acid

The former compound displays a remarkable three-dimensional architecture sustained by the catenation of 2D bilayers, while the latter exhibits a unique twofold interpenetrating three-dimensional architecture. The thermal and fluorescence properties associated with their crystal structures have been measured.



  5-Nitro-1, 3-Benzenedicarboxylic Acid

Two novel cadmium(II) coordination compounds, [Cd(bpe)1.5(NO2-BDC)]·0.25H2O (1) and [Cd(bpp)(NO2-BDC)(H2O)]·0.25H2O (2) [NO2-BDCH2 = 5-nitro-1,3-benzenedicarboxylic acid, bpe = 1,2-bis(4-pyridyl)ethane, bpp = 1,3-bis(4-pyridyl)propane] have been hydrothermally synthesized by reaction of cadmium chloride and NO2-BDC with the homologous ligands bpe and bpp, respectively.



  5-nitro Isophthalic Acid Dimethyl Ester

A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [{Co(dpe)(NO2-BDC)}·0.5(dpe)]n·nH2O (1), possessing nanoscale rectangular channels that clathrate large organic molecules, has been hydrothermally synthesized by reaction of cobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO2-H2BDC) and 1,2-bis(4-pyridyl)ethylene




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